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Experimental and Ab initio studies of intramolecular Ph/Cl exchange on Wilkinson’s catalyst and ligand-centered electrochemistry of ligand substituted metal carbonyls (M = Cr, Mo, W, Ir)
(2012)
Cyclic voltammetry measurements on (η2 -C60)M(CO)5 complexes (M = Cr, Mo, W) and on (C5H10N)3(H)3C60 in dichloromethane showed three C60-centered and reversible reduction/oxidation waves. The E1/2 values of these waves are ...
Consecutive solvent – C60 exchange on (η2– C60) Ir(CO)Cl(PPh3)2 and catalytically significant organometallic reactions on Ir(CO)(PPh3)2Cl(Solvent)
(2010)
The solvent/C60 exchange reactions on (η2 – C60)Ir(CO)(PPh3)2Cl (solvent = benzene and cyclohexane) are biphasic. Plots of absorbance values at 550 nm vs. time are biexponential. Experiments where the reactions were monitored ...
Ligand displacement reactions of fac-(η2-C60)(η2-phen)M(CO)3 (M = Mo, Cr, and W)
(2009)
A mechanistic description of the ligand exchange reactions of fac-(η2-C60)(η2-phen)M(CO)3 (M = Cr, W and Mo); phen = 1,10-phenanthroline) will be presented in this work. The Lewis bases (L) piperidine (pip), triphenyl ...
Empirical relationships using the total oxidation number of neighboring carbon atoms to predict 13C chemical shifts in hydrocarbons
(2018-05)
The focus of this research is to probe if the oxidation number concept is not merely theoretical, but a term that is related to measurable chemical and physical properties of an atom in a molecule. Selected acyclic ...
Functionalization of [60]Fullerene using organometallic complexes and amines
(2008)
The organometallic functionalization of C60 can produce novel materials with potential applications in fields such as material science, electronics, and catalysis. Understanding the structure-dependent electronic and ...