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dc.contributor.advisorRinaldi, Carlos
dc.contributor.authorCalero-Díaz del Castillo, Victoria L.
dc.date.accessioned2018-05-16T16:44:54Z
dc.date.available2018-05-16T16:44:54Z
dc.date.issued2005-09
dc.identifier.urihttps://hdl.handle.net/20.500.11801/610
dc.description.abstractWith the objective of developing a magnetic nanoparticle based sensor, we have synthesized cobalt-substituted ferrite particles using reverse micelles. Reverse micelles have been used to control the nanoparticle size. Cobalt ferrite was chosen due to its high anisotropy constant which assures that the relaxation mechanism is Brownina. Fe:Co ratios of 3:1, 4:1, and 5:1 were used in the synthesis, obtaining cobalt-substituted ferrites (CoxFe3-xO4). Inductively coupled plasma mass spectroscopy (ICP-MS) verified the presence of cobalt in all samples. Fourier transform infrared (FTIR) spectra show bands at ~560 and ~400 cm-1, confirming the metal-oxygen bond characteristic of ferrites. Transmission electron microscopy shows that the average size of the particles was ~3 nm with a geometric deviation of ~0.2. X-ray diffraction (XRD) confirmed the inverse spinel structure typical of ferrites with a lattice parameter of a = 8.388Å for Co0.61Fe0.39O4, which is near that of CoFe2O4 ( a = 8.39 Å). Magnetic properties were determined using a Superconducting Quantum Interference Device (SQUID). Coercivities (Hc) higher than 8 kOe were observed at 5 K, whereas at 300K the particles showed superparamagnetic behavior. The anisotropy constant was determined based on the Debye model for a magnetic dipole in an oscillating field. We obtained an expression relating χ ' and the temperature of the in-phase susceptibility peak. Anisotropy constant values in the order of ~106 kerg/cm3 were determined, using the Debye model, whereas anisotropy constants in the order of ~107 kerg/cm3 were calculated assuming Ωτ =1 at the temperature peak of the in-phase component of the susceptibility curve.en_US
dc.description.sponsorshipNASA-URC, National Science Foundationen_US
dc.language.isoenen_US
dc.subjectNanoparticlesen_US
dc.subjectReverse micellesen_US
dc.subjectCobalt ferriteen_US
dc.subject.lcshReversed micelles.en_US
dc.subject.lcshNanotechnology.en_US
dc.subject.lcshNanoparticles.en_US
dc.subject.lcshCobalt--Magnetic properties.en_US
dc.titleSynthesis and characterization of cobalt-substituted ferrite nanoparticles using reverse micellesen_US
dc.typeThesisen_US
dc.rights.licenseAll rights reserveden_US
dc.rights.holder(C) 2005 Victoria L. Calero Díaz del Castilloen_US
dc.contributor.committeePerales-Perez, Oscar
dc.contributor.committeeTorres-Lugo, Madeline
thesis.degree.levelM.S.en_US
thesis.degree.disciplineChemical Engineeringen_US
dc.contributor.collegeCollege of Engineeringen_US
dc.contributor.departmentDepartment of Chemical Engineeringen_US
dc.description.graduationYear2005en_US


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    Items included under this collection are theses, dissertations, and project reports submitted as a requirement for completing a graduate degree at UPR-Mayagüez.

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